单体
碳酸乙烯酯
化学
复分解
有机化学
丁香酚
聚碳酸酯
试剂
高分子化学
聚合物
聚合
电极
电解质
物理化学
作者
Xiankui Zeng,Qin Chen,Changbo Zhao,Sibo Xie,Haibo Xie,Caijuan Huang
标识
DOI:10.1002/asia.202200503
摘要
The significant development of catalytic biomass conversion has provided a large library of chemicals ready for subsequent upgrading to polymerisable monomers for the design and preparation of sustainable polymers. In this study, hydroxyethylation of eugenol by using green ethylene carbonate as alkylation reagent and cheap tetrabutylammonium iodide ionic liquids as green solvents and catalysts produced 2-(4-allyl-2-methoxyphenoxy)ethan-1-ol with a 85% yield, which could be used to construct an in situ CO2 capture and conversion system by taking the reversible chemistry of alcoholic compounds with CO2 in the presence of superbases, on which α,ω-diene functionalized carbonate monomers were successfully prepared and were applied in thiol-ene click and acyclic diene metathesis polymerisation (ADMET), producing a series of poly(thioether carbonate)s and unsaturated aromatic aliphatic polycarbonates with moderate molecular weights and satisfactory thermal properties. The structures of the formed CO2 reversible ILs, the polymerisable monomers and the corresponding polymers were fully characterized by various technologies.
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