膨胀的
材料科学
阻燃剂
极限氧指数
醋酸乙烯酯
可燃性
胶粘剂
复合材料
烧焦
锥形量热计
聚合物
化学工程
共聚物
高分子化学
热解
图层(电子)
工程类
作者
Jinhan Lu,Luming Li,Peng Jiang,Zhilin Chen,Gaelle Fontaine,Yahui Zhang,Guoping Yu,Serge Bourbigot
出处
期刊:Polymer
[Elsevier]
日期:2022-03-01
卷期号:245: 124709-124709
被引量:3
标识
DOI:10.1016/j.polymer.2022.124709
摘要
Melamine amino trimethyl phosphate (M-AT) has been mixed with bio-based starch, chitosan, or sodium lignosulfonate (SL), and used to prepare an intumescent flame retardant (IFR) vinyl acetate-ethylene copolymer emulsion (VAE), which might be used for the formulation of adhesives, coatings, etc . The goal was to meet the performance requirements especially with respect to flame retardance and mechanical properties. The flammability of VAE adhesives was assessed using limiting oxygen index (LOI), UL-94 vertical burning, and cone calorimetry tests (CCT). The presence of 30 wt% of the M-AT/SL compounds (mass ratio of M-AT to SL was 3:1) in VAE polymer brought a 73% reduction in peak of heat release rate (139.2–37.1 kW/m 2 ) in CCT. The LOI was increased to 31.5 from 20, the UL94 grade was upgraded to V-0 (sample thickness: 5 mm). The formation of bubble-shaped char layer can be promoted by polyphosphoric acid and benzenesulfonic acid along with ammonia and sulfur dioxide, which generated by the thermal decomposition of synthesized M-AT and SL during combustion of the polymer. In addition, the incorporation of 30 wt% M-AT/SL compounds in VAE matrix leaded to a 56% and 40% increasement in tensile strength and elongation at break tests, respectively compared to the pure one. This work offers a green and novel method for the production of high-performance VAE adhesives with fire resistance properties. • A novel intumescent flame retardant system for VAE polymer proposed. • Intumescent VAE polymer with excellent flame retardance, thermal stability, and mechanical properties. • Evolution of intumescent char layer investigated. • Mechanism of flame-retardance investigated.
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