化学
钳子运动
钌
酰化
催化作用
有机化学
氢
解放
生物化学
体外
作者
Boopathy Gnanaprakasam,Yehoshoa Ben‐David,David Milstein
标识
DOI:10.1002/adsc.201000663
摘要
Abstract Acylation of secondary alcohols using non‐activated esters, in particular symmetrical esters (such as ethyl acetate), is achieved under neutral conditions with the liberation of molecular hydrogen. This unprecedented, environmentally benign reaction is homogenously catalyzed by a dearomatized ruthenium pincer PNN complex.
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