光催化
化学
可见光谱
辐照
扫描电子显微镜
热液循环
复合数
微观结构
价带
复合材料
核化学
化学工程
光化学
催化作用
带隙
材料科学
光电子学
结晶学
有机化学
物理
工程类
核物理学
作者
Hai-Yan Zhou,Yin Peng,Shuchun Qin
标识
DOI:10.1002/cjoc.201180401
摘要
Abstract Bi 2 WO 6 microstructures were synthesized through hydrothermal process and Ag@Bi 2 WO 6 composites were synthesized by simple UV light irradiation for 5 min using Bi 2 WO 6 and AgNO 3 as raw materials. Ag@Bi 2 WO 6 composites were characterized by X‐ray powder diffraction (XRD), field‐emission scanning electron microscopy (FE‐SEM), and UV‐Vis absorption spectrum (UV‐Vis). Few Ag deposited on the Bi 2 WO 6 leads to an increase in photocatalytic activity, which clearly indicates that the recombination of photogenerated charge carrier between the hybrid orbital of Bi6s and O2p (valence band) to the empty W5d orbital is inhibited greatly in the Ag@Bi 2 WO 6 composite. In addition, a few H 2 O 2 will greatly enhance photocatalytic activity of Ag@Bi 2 WO 6 , and the proper reason is discussed.
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