催化作用
硼氢化钠
甲醇
X射线光电子能谱
脱氢
拉曼光谱
兴奋剂
氧气
傅里叶变换红外光谱
碳纤维
打赌理论
材料科学
核化学
化学
无机化学
化学工程
有机化学
工程类
复合材料
物理
光学
复合数
光电子学
出处
期刊:Fuel
[Elsevier]
日期:2022-02-01
卷期号:310: 122444-122444
被引量:37
标识
DOI:10.1016/j.fuel.2021.122444
摘要
g-C3N4, which is used in different catalytic activities, was applied to the H2 field from NaBH4 methanolysis for the first time in this study. The development of g-C3N4 is necessary to make it a viable alternative to the heterogeneous catalysts currently used in this field. The g-C3N4 used in this study contains both carbon vacancies and oxygen doping atoms. Compared to the g-C3N4 catalyst, the O doped g-C3N4 catalyst obtained showed an approximately 3.4-fold improvement in H2 production. The HGR value obtained with O doped g-C3N4 (5 mg) was 10800 ml min−1 g−1. The structural properties of the obtained catalysts were characterized by XPS, SEM-EDX, TEM, FTIR, Raman, BET and XRD analyses. These analyses showed significant changes for O doped g-C3N4. The activation energy obtained for O doped g-C3N4 was approximately 36.13 kJ mol−1.
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