光催化
六价铬
光电流
石墨烯
材料科学
纳米棒
光致发光
氧化物
化学工程
纳米复合材料
催化作用
铬
热液循环
纳米技术
化学
光电子学
冶金
工程类
生物化学
作者
A. Raja,Namgyu Son,Misook Kang
标识
DOI:10.1016/j.seppur.2021.119872
摘要
A reduced graphene oxide (rGO)-Gd2MoO6-ZnO nanocomposite was synthesized using a hydrothermal method, in which rod-shaped ZnO and plate-like Gd2MoO6 were decorated on rGO sheets. The as-prepared photocatalyst was characterized using X-ray diffraction, optical studies, photoluminescence measurements, surface morphology, chemical states, and photocurrent density studies. A stable photocatalytic performance was achieved using the synergetic Gd2MoO6-rGO-ZnO composite catalyst during the reduction of Cr(VI) to benign Cr(III) compared with the performance achieved using bare and binary composite catalysts. The effects of various parameters, such as different weight ratios and solution pH, were investigated. An optimized pH of 4 was used for the effective reduction of Cr(VI) to Cr(III). The maximum photocatalytic reduction performance (94.5%) was achieved within 160 min. Photocurrent density and PL emission measurements confirmed the fast charge transfer and effective charge separation over Gd2MoO6-rGO-ZnO, which improved the Cr(VI) reduction. A photocatalytic Cr(VI) reduction mechanism for Gd2MoO6-rGO-ZnO was proposed.
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