材料科学
电介质
介电谱
粒度
陶瓷
晶界
极化(电化学)
储能
凝聚态物理
复合材料
微观结构
热力学
物理化学
光电子学
电极
功率(物理)
电化学
化学
物理
作者
Zhe Song,Hanxing Liu,Shujun Zhang,Zhijian Wang,Yatong Shi,Hua Hao,Minghe Cao,Zhonghua Yao,Zhiyong Yu
标识
DOI:10.1016/j.jeurceramsoc.2013.11.039
摘要
(Ba0.4Sr0.6)TiO3 (BST) ceramics with various grain sizes (0.5–5.6 μm) were prepared by conventional solid state reaction methods. The effect of grain size on the energy storage properties of BST ceramics (Tc ≈ −65 °C) was investigated. With decreasing grain sizes, a clear tendency toward the diffuse phase transition was observed and the dielectric nonlinearity was reduced gradually, which can be explained by the Devonshire's phenomenological theory (from the viewpoint of intrinsic polarization). Based on the multi-polarization mechanism model, the relationship between the polarization behavior of polar nano-regions (the extrinsic nonlinear polarization mechanisms) and grain size was studied. The variation of the grain boundary density was thought to play an important role on the improvement of dielectric breakdown strength, account for the enhanced energy density, which was confirmed by the complex impedance spectroscopy analysis based on a double-layered dielectric model.
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