材料科学
铁电性
储能
接口(物质)
聚合物
铁电聚合物
化学工程
分子工程
光电子学
有机半导体
纳米技术
超级电容器
工程物理
制作
作者
Yang Cui,Yu Feng,Tiandong Zhang,Changhai Zhang,Qingguo Chi,Yongquan Zhang,Xuan Wang,Qingguo Chen,Qingquan Liu
标识
DOI:10.1021/acsami.0c16197
摘要
Ferroelectric polymers are regarded as the preferred material in dielectric energy storage devices because of their high dielectric constant. However, their relatively low breakdown strength and efficiency restrict their practical application. This work combines coaxial spinning and hot pressing to compound the highly insulating linear poly(methyl methacrylate) (PMMA) and ferroelectric poly(vinylidene fluoride) (PVDF) to obtain a PMMA/PVDF all-organic film with a ferroconcrete-like structure. Further, improvements in the energy storage performance over those of the pristine polymer were achieved via modulation of the PMMA to PVDF ratio. The 45% PMMA/PVDF film had an energy storage density of 17.7 J/cm3 and an energy efficiency of 73% at 640 kV/mm. Moreover, 51% PMMA/PVDF exhibited the best energy storage density (U = 20.7 J/cm3, η = 63% at 630 kV/mm). This work, therefore, provides a new idea for the design of all-organic polymer films for the field of energy storage.
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