Ag(I)-Catalyzed Tandem Reaction of Conjugated Ene-yne-ketones in the Presence of PhI(OAc)2 and Triethylamine: Synthesis of 2-Alkenylfurans

Silver-catalyzed tandem cyclization–elimination reactions of conjugated ene-yne-ketones in PhI(OAc)2/triethylamine system lead to the formation of 2-alkenylfurans. 2-Furylsilver carbene and phenyliodonium ylide are proposed as the key intermediates in these transformations.