光催化
异质结
X射线光电子能谱
材料科学
载流子
煅烧
石墨氮化碳
无定形固体
氮化碳
降级(电信)
兴奋剂
光化学
化学工程
光电子学
化学
催化作用
结晶学
有机化学
电信
工程类
计算机科学
作者
Xiaoyan Huang,Xiuyun Zhang,Kexiang Zhang,Xiaogang Xue,Jian Xiong,Yu Huang,Doudou Zhang,Jian Zhang,Zheling Zhang,Fengpo Yan
标识
DOI:10.1016/j.jallcom.2021.160321
摘要
Constructing Z-scheme photocatalysts is a promising strategy to improve the photocatalytic performance of materials, wherein carriers’ recombination plays a critical role by tuning carrier transportation and separation. In this study, a defect mediated layered heterojunction of amorphous carbon nitride (A-CN) and carbon doped ZnO (C-ZnO) are designed by calcination of ZIF-8 immersed urea. TEM and SEM elucidate the 2D heterojunctions coupled C-ZnO with a sheet-like A-CN that was formed. FTIR and XPS confirm the existence NCN and NCN groups interacted with C-ZnO. The defect-mediated C-ZnO/A-CN with 75% A-CN exhibited the highest tetracycline hydrochloride (TC) degradation rate, ~7.7, 3.0 and 7.7 times that of ZnO, loaded ZnO+CN or CN, respectively. Transient PL and photochemical characterizations revealed that defects assisted carriers’ recombination leads to a strong Z-scheme interfacial charge transfer and more reactive centers for TC degradation. This work would provide a new insight for the design of Z-scheme photocatalysts for the removal of pollutants.
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