Tailoring activation of CoNiO nanoparticles/porous carbon nanofibers by atomic doping for high performance supercapacitors

(nearly no degradation after 6000 cycles). Density Functional Theory (DFT) calculations indicate that the Ni doping models present lower formation energy and better -OH group adsorption properties. Moreover, the density of electronic state (DOS) and differential charge density distribution demonstrate that Ni doping effectively enhances the charge transport during the charging and discharging processes, which is beneficial to enhance the energy storage of the electrode materials. In conclusion, this work presents a strategy to design MOF-derived composite electrodes. The experimental tests and theoretical calculations explore the energy storage process and prove that the CoNiO/PCNF electrode materials have great potential for applications.