化学
喹啉
脱氢
组合化学
催化作用
位阻效应
配体(生物化学)
串联
喹唑啉
钴
不饱和度
立体化学
有机化学
受体
生物化学
材料科学
复合材料
作者
Debjyoti Pal,Avijit Mondal,Rajashri Sarmah,Dipankar Srimani
出处
期刊:Organic Letters
[American Chemical Society]
日期:2024-01-09
卷期号:26 (2): 514-518
标识
DOI:10.1021/acs.orglett.3c03944
摘要
In this work, we have constructed three new Co(II) complexes in which steric features govern their structural geometry. The metal ligand-cooperation behavior of the alkoxy arm is utilized to explore the catalytic activities of these complexes with respect to dehydrogenation. A wide range of C-3-substituted quinoline and quinazoline derivatives were synthesized in high yields. The developed protocol’s usefulness is enhanced by the chemoselective transformation of different fatty alcohols to synthesize heterocycles having distal unsaturation. Various kinetic, mechanistic, and control studies were conducted to comprehend the reaction route.
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