催化作用
氧气
析氧
金属有机骨架
氢
金属
配体(生物化学)
氧还原反应
纳米技术
化学
材料科学
组合化学
化学工程
有机化学
电化学
物理化学
冶金
电极
受体
吸附
工程类
生物化学
作者
Jie Bai,Jia Wang,Ping Liu,Jiancheng Huang,Xuefang Shang,Shujun Chao
标识
DOI:10.1016/j.ijhydene.2022.07.011
摘要
Design and development of cost-efficient multifunctional three-dimensional (3D) metal organic frameworks (MOFs) towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are very significant for green energy devices. Herein, a scalable one-pot solvothermal method is developed to obtain a series of multifunctional 3D flower-like MOFs. In addition, systematic studies are also conducted on the effects of various metal cations and N-containing ligands on the structures, compositions, and multifunctional performance of the obtained MOFs. As a result, 3D flower-like Co-MOFs using Co2+ as a metal cation and 2,2’:6′,2″-terpyridine as a N-containing ligand exhibit the highest multifunctional performance towards ORR, OER and HER. The scalable method provides a new prospect to design and develop other MOFs-based multifunctional catalysts.
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