化学
邻接
可见光谱
键裂
催化作用
光化学
药物化学
立体化学
劈理(地质)
有机化学
断裂(地质)
光电子学
物理
工程类
岩土工程
作者
Yaohong Zhao,Shunyou Cai,Jing Li,David Zhigang Wang
出处
期刊:Tetrahedron
[Elsevier]
日期:2013-09-01
卷期号:69 (38): 8129-8131
被引量:25
标识
DOI:10.1016/j.tet.2013.07.056
摘要
A range of 1,2-vicinal diamines were smoothly converted into N,N-dialkylformamides under the synergistic actions of Ru(bpy)3Cl2 photo-catalyst, 45 W household lighting bulb, and Cs2CO3 basic additive under very mild reaction conditions. The process involves visible light-enabled photo-catalytic cleavage of C–C bond as the strategic event.
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