Controllable synthesis of 3-iodo-2H-quinolizin-2-ones and 1,3-diiodo-2H-quinolizin-2-onesviaelectrophilic cyclization of azacyclic ynones

An efficient approach was developed to divergently synthesize 3-ipdo-2H-quinolizin-2-ones and 1,3-diiodo-2H-quinolizin-2-ones from azacyclic ynones with high regioselectivity under metal-free, room temperature conditions in air.