纳米复合材料
壳聚糖
检出限
水溶液
电化学气体传感器
电化学
碳糊电极
化学工程
银纳米粒子
化学
选择性
电极
聚合物
材料科学
核化学
纳米技术
纳米颗粒
色谱法
有机化学
循环伏安法
物理化学
工程类
催化作用
作者
Naif Khalaf,Tansir Ahamad,Mu. Naushad,Noorah Al-hokbany,Sameerah I. Al‐Saeedi,Sultanah Almotairi,Saad M. Alshehri
标识
DOI:10.1016/j.ijbiomac.2019.11.193
摘要
N/S-doped carbon supported AgNPs has been synthesized at low-cost, and scalable method using silver complex of chitosan based polymer. The fabricated nanocomposites exhibited excellent electrocatalytic performance as a glucose sensor. Remarkably, the fabricated glucose sensor is exhibited an ultrahigh sensitivity of 35.22 mAmM−1 cm−2 with a very low detection limit (0.046 mM) and long-term durability (30 days). Under optimized conditions, a wide linear response was obtained from 5 μM to 3 mM with an excellent linear response (R2 = 0.9940) was also obtained by AgNPs/NSC modified electrode. The presence of the heteroatom and AgNPs into the carbon matrix greatly enhances the selectivity for glucose over potential interferences in aqueous solution, with interfering agents. Overall, the present methodology demonstrates an efficient, robust, and aqueous-media-tolerable nanocomposite material as an electrochemical sensor and a potential alternative tool for the detection of glucose.
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