吸附
水溶液
表面改性
化学
发光
金属有机骨架
选择性吸附
高锰酸盐
无机化学
铬酸盐转化膜
材料科学
有机化学
铬
物理化学
光电子学
作者
Harpreet Kaur,Sidharth Walia,Anirban Karmakar,Venkata Krishnan,Rik Rani Koner
标识
DOI:10.1016/j.jece.2021.106667
摘要
Given the importance of surface-functionalized materials with improved adsorption and detection properties for targeted applications, we report herein the design and development of a water-stable luminescent Zn-based metal-organic framework (Zn-MOF) with the hydrophobic-hydrophilic surface property. The developed luminescent Zn(II)-MOF {[Zn(PA2-)(dmbpy)](DMF)}n was synthesized via a solvothermal method using pamoic acid (PA) and 5,5′-dimethyl-2,2′-bipyridine (dmbpy) with free functional groups (hydroxyl and methyl groups). Careful single-crystal structure analysis revealed a 3-dimensional hydrogen-bonded network with a one-dimensional channel and functionalized surface. The surface functionalization was achieved through rational choice of ligands bearing methyl and hydroxyl groups as suitable hydrophobic and hydrophilic functionalities respectively, leading to a stable MOF in the aqueous medium. The MOF was used as an adsorbent for selective adsorption of monovalent permanganate anion (MnO4-) over other polyvalent oxo-anions as well as an optical platform for the detection of oxo-anions (permanganate (MnO4-), dichromate (Cr2O72-) and chromate (CrO42-)) and pesticide (2,6-dichloro-4-nitroaniline (2,6-DCNA)) in the aqueous medium. Overall, a combination of luminescent nature and hydrophilic-hydrophobic surface property makes the developed Zn-MOF an interesting platform for environmental application.
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