膜
极限抗拉强度
芳基
苯乙烯
共聚物
化学
电导率
离子交换
材料科学
相对湿度
离子
高分子化学
复合材料
聚合物
有机化学
烷基
物理化学
热力学
物理
生物化学
作者
Nanjun Chen,Chuan Hu,Ho Hyun Wang,Jong Hyeong Park,Hae Min Kim,Young Moo Lee
标识
DOI:10.1016/j.memsci.2021.119685
摘要
Poly(aryl-co-aryl piperidinium) (c-PAP) copolymers have recently demonstrated great successes in anion exchange membranes (AEMs) and ionomers for AEM fuel cells (AEMFCs). Here, we present a series of in-situ styrene-crosslinked c-PAP (x-PAP-PS) membranes to further enhance the mechanical strength, dimensional stability, and water retention capacity of c-PAP AEMs. Specifically, x-PAP-PS AEMs simultaneously possess high ion conductivity (>150 mS cm−1), tensile strength (>80 MPa), and chemical and mechanical durability (~90 % ion conductivity and mechanical strength maintaining in 1 M NaOH at 80 °C for 2160 h). Additionally, x-PAP-PS-based AEMFCs reached peak power densities (PPDs) of 2.23 W cm−2 in H2–O2 and 1.32 W cm−2 in H2-air at 80 °C. Importantly, compared to pristine c-PAP AEMs, x-PAP-PS AEMs display higher water retention capacity at low relative humidity (RH), and the corresponding AEMFCs reach PPDs >1 W cm−2 with Pt/C at 30 %/30 % RH at 90 °C. Moreover, the x-PAP-PS-based AEMFCs can be operated stably under a 0.4 A cm−2 current density at 60 °C for ~120 h.
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