木质素
材料科学
极限抗拉强度
纤维素
透射电子显微镜
半纤维素
复合材料
核化学
化学工程
化学
生物化学
纳米技术
有机化学
工程类
作者
Gu-Joong Kwon,Seung‐Woo Cho,Rajkumar Bandi,Bong-Suk Yang,Ramakrishna Dadigala,Sang‐Ik Han,Seo-Young Ma,Jeong-Ki Kim,Namhun Kim,Seung Hwan Lee
出处
期刊:Cellulose
[Springer Nature]
日期:2023-04-01
卷期号:30 (7): 4277-4292
被引量:4
标识
DOI:10.1007/s10570-023-05164-1
摘要
Herein for the first time, lignocellulose nanofibrils (LCNF) were prepared from pine-wood powder using microwave (MW)-assisted deep eutectic solvent (DES) pretreatment coupled with high-pressure homogenization. A DES based on choline chloride and lactic acid was employed, and LCNFs prepared by conventional DES pretreatment at 110 °C (LCNF-110) and 130 °C (LCNF-130) were used for comparison. Although MW treatment offered a high removal of lignin (70%) and hemicellulose (90%) within a short time (110 s), the morphological observations by scanning and transmission electron microscopies revealed excellent nanofibrillation of the conventionally heat-treated samples. Likewise, LCNF-110 and LCNF-130 exhibited high tensile strengths of 154.6 ± 5.0 and 136.8 ± 1.2 MPa, respectively, whereas that of LCNF-MW was only 75.6 ± 1.4 MPa. Interestingly, LCNF-MW with a lignin content between that of LCNF-110 and LCNF-130 exhibited high thermal stability (Tmax 309.6 °C) and potent antioxidant properties. However, the lignin contents of the LCNFs determined their UV-radiation blocking efficiency, where LCNF-110 > LCNF-MW > LCNF-130. Furthermore, all LCNF films exhibited good visible-light transparency, flexibility, and water contact angles (> 87°), indicating their promising potential for packaging applications.
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