氢解
催化作用
甘油
热解
化学
铜
氧烷
尖晶石
无机化学
核化学
材料科学
冶金
有机化学
光谱学
量子力学
物理
作者
Naphaphan Kunthakudee,Pongtanawat Khemthong,Chuleeporn Luadthong,Joongjai Panpranot,Okorn Mekasuwandumrong,Thongthai Witoon,Kajornsak Faungnawakij
标识
DOI:10.1016/j.mcat.2021.111426
摘要
The catalysts of copper aluminates (CuAl2O4), copper oxide (CuO), and alumina (Al2O3) synthesized via one-step flame-spray pyrolysis (FSP) with various mole ratios of Cu to Al have been studied in the hydrogenolysis of glycerol, a byproduct from the biodiesel industry, to 1,2-propanediol (1,2-PDO) at 220 °C under 50 bar of H2 for 6 h. The studies on the CuAl2O4 nanoparticles reveal that their formation and particle size depend upon the mole ratio of Cu to Al, and they possess a structure analogous to that of the bulk material. The X-ray absorption near edge spectroscopy (XANES) data along with X-ray diffraction (XRD) patterns confirmed the formation of a CuAl2O4–CuO–Al2O3 mixed phases. The characteristic CuAl2O4 species was dominant during the flame process when a low content of Cu to Al, such as a 1:5 mol ratio, was supplied. It was observed that the CuAl2O4 combined with the CuO and Al2O3 phases exerts a strong positive effect on the catalytic activity. A selectivity to 1,2-PDO of 91.7% was observed for the synthesized catalyst with a 1:1 mole ratio of Cu to Al. The developed catalyst was superior to the conventional CuO-based ones in the hydrogenolysis of glycerol process.
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