材料科学
X射线光电子能谱
纳米纤维
化学工程
超级电容器
循环伏安法
静电纺丝
扫描电子显微镜
钙钛矿(结构)
煅烧
拉曼光谱
比表面积
电化学
电极
纳米技术
化学
复合材料
催化作用
有机化学
光学
物理化学
工程类
物理
聚合物
作者
Quanli Hu,Bin Yue,F. Yang,Hongyang Shao,Jinghui Wang,Lei Ji,Yongfeng Jia,Yin Wang,Jinghai Liu
标识
DOI:10.1002/slct.201903426
摘要
Abstract Perovskite‐type CeMnO 3 nanofibers (NFs) were effectively synthesized via electrospinning and consequent calcination processes. The nanofibers with porous surface exhibit a high specific surface area of 103.88 m 2 g −1 with mesopores. The perovskite CeMnO 3 NFs were characterized by X‐ray diffraction, Raman spectroscopy, UV‐vis diffuse reflectance spectrum, and X‐ray photoelectron spectroscopy. The microstructure and morphology of CeMnO 3 were observed by scanning electron and transmission electron microscopes. The Energy‐dispersive X‐ray spectroscopy manifested the homogeneous distribution of cerium, manganese, and oxygen. The electrochemical properties of CeMnO 3 NFs were implemented using cyclic voltammetry and galvanostatic charge‐discharge in alkaline aqueous electrolyte. The Faradic redox reaction occurred at the electrode surface was precisely concluded. The specific capacitance of CeMnO 3 NFs was 159.59 F g −1 at the current density of 1 A g −1 . This research offers a new strategy to synthesize CeMnO 3 perovskite material for high‐performance supercapacitor, indicating its potential application as a supercapacitor electrode in energy storage devices.
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