多元醇
聚氨酯
硅醇
离子键合
化学工程
高分子化学
材料科学
棉籽油
化学
有机化学
二醇
纳米纤维
催化作用
离子
食品科学
工程类
作者
Sashivinay Kumar Gaddam,S. N. Raju Kutcherlapati,Aruna Palanisamy
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2017-07-11
卷期号:5 (8): 6447-6455
被引量:49
标识
DOI:10.1021/acssuschemeng.7b00327
摘要
Phosphorylated polyols (phospols) derived from cottonseed oil (CSO) were employed to synthesize novel, DMPA- (dimethylol propanoic acid-) free, catalyst-free, waterborne polyurethane dispersions (PUDs). Three different phospols bearing both hydroxyl and ionizable phosphoryl groups were synthesized through the ring-opening hydrolysis of epoxidized cottonseed oil (ECSO) in the presence of ortho-phosphoric acid. The phospols were characterized by 1H NMR spectroscopy, FTIR spectroscopy, and gel permeation chromatography. Three phospols (phospol-P5, -P10, and -P15) having hydroxyl numbers of 130, 160, and 180 mg of KOH/g, respectively, were used as internal emulsifiers in waterborne PUDs with isophorone diisocyanate and 3-aminopropyltriethoxysilane (APTES). All three PU dispersions showed excellent storage stabilities (>6 months), and the average particle sizes of the PUDs ranged from 30 to 68 nm. The cured films were characterized by FTIR (ATR) and solid-state 29Si NMR analyses. The hydrophobicities of the fi...
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