Titanium lanthanum three oxides decorated magnetic graphene oxide for adsorption of lead ions from aqueous media

吸附 材料科学 石墨烯 氧化物 镧 纳米复合材料 水溶液 无机化学 弗伦德利希方程 朗缪尔吸附模型 朗缪尔 化学工程 化学 纳米技术 冶金 物理化学 工程类
作者
Nazanin Mosleh,Parham Joolaei Ahranjani,Ehsan Parandi,Hamid Rashidi Nodeh,Nicole Nawrot,Shahabaldin Rezania,Palanivel Sathishkumar
出处
期刊:Environmental Research [Elsevier BV]
卷期号:214 (Pt 2): 113831-113831 被引量:46
标识
DOI:10.1016/j.envres.2022.113831
摘要

The current study presents a viable and straightforward method for synthesizing titanium lanthanum three oxide nanoparticles (TiLa) and their decoration onto the ferrous graphene oxide sheets to produce FeGO-TiLa as efficient magnetic adsorbent. Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and vibration sample magnetometer (VSM) were used to evaluate the physical and chemical properties of the produced nanocomposites. The FeGO-TiLa was used to enhance the removal of lead ions from aquatic media. The FeGO-TiLa nanocomposite exhibited a much higher removal efficiency (93%) for lead ions than pure TiLa nanoparticles (81%) and magnetic graphene oxide (74%). The influence of FeGO-TiLa dosage, contact time, solution pH, solution temperature, and starting quantity on the lead ions was evaluated and adjusted. The investigations demonstrated that a pH 6 with 40 mg adsorbent resulted in a >91% removal of lead ions at ambient temperature after 120 min. Isotherm models were used to analyze experimental results, and a Langmuir model fitted the data well as compared Freundlich model with a maximum adsorption capacity of 109.89 mg g −1 . Kinetic and studies are performed the lead adsorption over FeGO-TiLa follow pseudo-second-order rate. Langmuir and Free energy suggested the lead ions uptake with FeGO-TiLa was monolayer and physical adsorption mechnaism, respectively. Finally, the FeGO-TiLa nanocompoiste can be used as an alternative adsorbent for water remediation. • Novel titanium lanthanum oxide nanoparticles doped iron graphene oxide was used. • The FeGO-TiLa as magnetic adsorbent was used to enhance the removal of lead from water. • The FeGO-TiLa had a higher removal (93%) for lead than pure LaTiO3 (81%). • Langmuir suggested the lead ions uptake with FeGO-TiLa was a monolayer.
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