荧光粉
发射强度
材料科学
钇
热的
分析化学(期刊)
强度(物理)
微晶
退火(玻璃)
热发射
兴奋剂
光电子学
化学
复合材料
光学
冶金
热力学
物理
环境化学
氧化物
作者
Tamara V. Gavrilović,Jovana Periša,Zoran Ristić,Karolina Elżbieciak-Piecka,Ł. Marciniak,Chong‐Geng Ma,Željka Antić,D. Miroslav Dramićanin
出处
期刊:Measurement
[Elsevier]
日期:2022-10-01
卷期号:202: 111942-111942
被引量:6
标识
DOI:10.1016/j.measurement.2022.111942
摘要
We demonstrate the thermal history forensic measurements founded on the emission intensity ratio of Eu3+-doped yttrium vanadate. An increase in phosphor’s crystallite size with annealing temperature is observed, causing a significant and permanent increase in the emission intensity and symmetry ratio (ratio of Eu3+ 5D0 → 7F1 and 5D0 → 7F2 emissions). This ratio is used as a forensic indicator of the maximal temperature to which phosphor was exposed. Additionally, we demonstrated that irreversible change in the symmetry ratio after exposure to high temperatures is insensitive to the exposure time. Finally, it is shown that thermal history readings can be performed at any temperature. The applicative potential of the proposed approach was confirmed in the proof-of-concept experiment on a steel plate covered with phosphor and exposed to high temperatures.
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