聚氨酯
材料科学
碳纳米管
复合材料
极限抗拉强度
复合数
热稳定性
延伸率
拉伸试验
色散(光学)
X射线光电子能谱
化学工程
工程类
物理
光学
作者
YaSen Li,Yudong Shang,Jiangping He,Mingyue Li,Man Yang
标识
DOI:10.1016/j.diamond.2022.109427
摘要
The uniform dispersion of oxidized multi-wall carbon nanotubes (OCNT) in waterborne polyurethane (WPU) matrix was achieved by in-situ polymerization, endowing the OCNT/WPU composite film with enhanced tensile strength, thermal stability, and excellent elongation at break. The structure of multi-wall carbon nanotubes (CNT) and OCNT was characterized by TEM, XRD, XPS, and the structure and morphology of composites were characterized by particle size analysis, SEM and FT-IR. Compared with pure WPU and OCNT/WPU composite, the breaking strength and the thermal degradation temperatures of 20 % weight loss of the OCNT/WPU composite were increased by 175 % and 353 °C, respectively. The oxygen-containing functional groups effectively improved the surface active of OCNT, making it easier for OCNT to react with polyurethane prepolymers. After addition of only 1 % OCNT, the tensile strength approaches 77 MPa while the elongation at break remains at 277 %. In addition to having outstanding chemical and mechanical properties, OCNT have a better dispersibility rate than multiwalled carbon nanotubes, which means that they will have a broader application range.
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