PZT Optical Memristors

Optical memristors represent a monumental leap in the fusion of photonics and electronics, heralding a new era of new applications from neuromorphic computing to artificial intelligence. However, current technologies are hindered by complex fabrication, limited endurance, high optical loss or low modulation efficiency. For the first time, we unprecedentedly reveal optical non-volatility in thin-film Lead Zirconate Titanate (PZT) by electrically manipulating the ferroelectric domains to control the refractive index, providing a brand-new routine for optical memristors. The developed PZT optical memristors offer unprecedented advantages more than exceptional performance metrics like low loss, high precision, high-efficiency modulation, high stability quasi-continuity and reconfigurability. The wafer-scale sol-gel fabrication process also ensures compatible with standardized mass fabrication processes and high scalability for photonic integration. Specially, these devices also demonstrate unique functional duality: setting above a threshold voltage enables non-volatile behaviors, below this threshold allows volatile high-speed optical switching. This marks the first-ever optical memristor capable of performing high-speed signal processing and non-volatile retention on a single platform, and is also the inaugural demonstration of scalable functional systems. The PZT optical memristors developed here facilitate the realization of novel paradigms for high-speed and energy-efficient optical interconnects, programmable PICs, quantum computing, neural networks, in-memory computing and brain-like architecture.