泛音
化学
甲烷
光谱学
吸收(声学)
可调谐激光吸收光谱技术
噪音(视频)
吸收光谱法
二极管
光电子学
红外光谱学
红外线的
激光器
光学
分析化学(期刊)
可调谐激光器
谱线
材料科学
物理
有机化学
人工智能
计算机科学
图像(数学)
色谱法
量子力学
天文
作者
Guolin Li,Siyu Zhang,Yajing Liu,Enting Dong,Lupeng Jia,Fuli Zhao,Yingjie Zhao,L.L. Li,Haoran Yuan,Guangzhao Cui,Ruixiang Sun
标识
DOI:10.1021/acs.analchem.4c03771
摘要
Based on tunable diode laser absorption spectroscopy and off-axis integrated cavity output spectroscopy, a dual-range methane hybrid sensor was constructed utilizing the overtone absorption band of CH4 gas molecules at 1653.7 nm. By simultaneously utilizing an off-axis integrated cavity and Herriott cell with an effective absorption path of 11 and 405 m, respectively, the two received photoelectric signals are decomposed into different frequency components by VMD and then reconstructed after SG filtering. Applying the global optimization algorithm DA-ELM to CH4 concentration inversion, the correlation coefficient R2 is as high as 0.9995. Through long-term stability verification, the instrument's standard deviation at 1 ppm is 27 ppb. After Allan-Werle deviation analysis, the sensor's limit of detection is 2.298 ppb at an integration time of 138 s. Using the self-developed sensor, the detection of dual-range trace CH4 gas is achieved, enabling a dynamic detection range of trace CH4 gas ranging from 400 ppb to 1000 ppm. The sensor realizes dual-range methane trace detection and actively controls methane emissions to improve environmental quality while taking into account the safety benefits of reducing production accidents.
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