The denitrification efficiency and nitrous oxide production during conventional biological denitrification and denitrification coupling with catalytic iron under different C/N ratio was studied.The results show that in both groups,the total nitrogen removal efficiency decreases while nitrous oxide production increases when C/N ratio becomes lower.But comparing control group,catalytic iron group has higher nitrate transforming efficiency and nitrous oxide emission.Futher more,the nitrous oxide could even be totally degraded when C/N was 1.