Smooth diamond like carbon(DLC)thin films are fabricated on silicon substrate by using filted cathodic vacuum arc(FCVA)deposition system.DLC thin films thermal stability is studied by using multi-wavelength laser excited by Raman spectroscopy.The experiment shows that thin films′microscopic structures can remain unchanged and stable when the films are thermally processed at a temperature of below 400℃.When the process temperature is raised to 600℃,the DLC films' atomic contents start to undergo subtle transformation,which is reviewed as metastable state.When the temperature is raised to800~1 000℃,DLC films start to change dramatically,and they will be graphitized and their physical characteristics cannot keep relatively stable.