Polybenzimidazole Ultrathin Anion Exchange Membrane with Comb-Shape Amphiphilic Microphase Networks for a High-Performance Fuel Cell

A comb-shape amphiphilic cationic side chain is proposed to well-balance the water sorption in anion exchange membranes (AEMs), in which the cationic group is in between of an ether-containing hydrophilic spacer and an alkyl hydrophobic spacer. By fully grafting the amphiphilic side chains onto polybenzimidazole (PBI), comb-shape amphiphilic microphase networks are well-developed in the AEMs, in which the alkyl hydrophobic network greatly restricts water swelling and the ether-containing hydrophilic network keeps the hydration of the cationic groups and enlarges the ion conductive channel. The as-prepared membranes achieve a high conductivity of about 91.2 mS cm^-1, an extremely low swelling ratio of about 8.1% at 80 °C, and good mechanical properties at a hydrated state (tensile strength and elongation at a break of about 14.6 MPa and 77.5%, respectively). Benefits from the balanced water sorption in AEMs, the H₂/O₂ fuel cell with a 10 μm ultrathin membrane could withstand 80 °C and 0.1 MPa back pressure and achieve a high open circuit voltage of about 1.0 V and a high peak power density of about 631.5 mW cm^-2. This work provides a new insight into the design of high-performance AEM.