X射线光电子能谱
材料科学
光催化
纳米复合材料
光致发光
无定形固体
化学工程
辐照
纳米结构
锆
Zeta电位
纳米技术
核化学
纳米颗粒
催化作用
光电子学
结晶学
化学
有机化学
冶金
工程类
核物理学
物理
作者
Md. Obaidullah,Takeshi Furusawa,Iqbal Ahmed Siddiquey,Newaz Mohammed Bahadur,Masahide Sato,Noboru Suzuki
标识
DOI:10.1016/j.apt.2018.04.016
摘要
[email protected]2 core-shell nanocomposites (NCs) were prepared by a novel and accessible path employing microwave (MW) irradiation to regulate photocatalytic property of ZnO. The synthesized [email protected]2 NCs were further examined to discern their optical and chemical properties by FT-IR, XPS, XRF, XRD, FE-SEM, EDX, TEM, UV–vis, and PL analysis. XPS data analysis confirmed the presence of zirconium and oxygen on the coated surface. An almost similar zeta potential curve was observed for the pure ZrO2 and ZrO2 coated ZnO NCs, predicting the presence of the ZrO2 layer on ZnO. Photoluminescence studies show the enhanced intensity of [email protected]2 nanostructure compared to uncoated ZnO. Photocatalytic activity of ZnO could be controlled by the amorphous ZrO2 layer, which was guaranteed by the photo mineralization of methylene blue under UV irradiation at room temperature.
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