结晶度
材料科学
结晶
高分子化学
缩聚物
碳酸二甲酯
季戊四醇
对苯二甲酸二甲酯
产量(工程)
聚合物
复合材料
化学
聚酯纤维
有机化学
催化作用
阻燃剂
作者
Seong Yeon Park,Jiseul Chun,Jong Yeob Jeon,Pyung Cheon Lee,Youn‐Ho Hwang,Bo Song,R.J. Ramos,Chang Y. Ryu,Hyun Ju Lee
摘要
Branched poly[1,4-butylene carbonate-co-terephthalate]s (PBCTs) have been synthesized by the addition of a small amount of glycerol propoxylate (1) or pentaerythritol (2) in the polycondensation of 1,4-butanediol, dimethyl carbonate, and dimethyl terephthalate. To avoid gel formation, the feed amount of 1 or 2 was carefully controlled at below 0.5 mol % for 1 and below 0.3 mol % for 2. When feed of 1 or 2 was used, a high-molecular weight melt state (Mw ∼180,000 g/mol) was reached in a total reaction time of 5.5 to 6.5 h with a yield higher than 90%. The generated PBCTs were a semicrystalline polymer (Tg ∼5 °C and Tm ∼120 °C) when the terephthalate content (F[TPA]) was 45 to 50 mol %. The crystallization rate increased with increasing F[TPA] and branch content (F[1 or 2]); PBCT composed of F[TPA] = 49 mol % and F[1] = 0.44 mol % was crystallized completely in a short time, ∼3 min, at a crystallization temperature of 50 °C. The branched PBCT exhibited more pronounced toughness in tensile test while providing the advantage of processibility at high shear rates due to the pronounced shear thinning in melt. It was also found that the branched PBCTs were biodegradable. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 914–923
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