层状结构
相(物质)
液晶
相图
水溶液
材料科学
层状相
六角相
甘油
衍射
化学
化学工程
色谱法
结晶学
有机化学
光学
物理
光电子学
工程类
作者
Justas Barauskas,Tomas Landh
出处
期刊:Langmuir
[American Chemical Society]
日期:2003-10-08
卷期号:19 (23): 9562-9565
被引量:290
摘要
Phytantriol, 3,7,11,15-tetramethyl-1,2,3-hexadecanetriol, is frequiently used as a cosmetic ingredient; however, very little is known about its physical and chemical properties. Here, we present the phase behavior of phytantriol in water, as determined by X-ray diffraction. At room temperature, the phase sequence upon increasing the water concentration is reversed micellar, lamellar, cubic phase Q230, and cubic phase Q224. At 44 °C, the cubic liquid crystals are transformed into a reversed hexagonal phase. The temperature−composition phase diagram of phytantriol/water mixtures is, thus, qualitatively similar to that of aqueous glycerol monooleate. The chemical stability of phytantriol makes it an interesting alternative to glycerol monooleate in exploiting various scientific and technical applications of, in particular, the cubic liquid crystalline phases.
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