Thermal Lens Technique: A New Method of Absorption Spectroscopy

Both a single beam and a dual beam (with synchronous detection) thermal lens technique have been employed in the measurement of "colorless" organic compounds in the range 15,700 to 17,400 cm -1 . Combination overtones of C-H stretching vibrations in benzene have been identified and agree with previous results obtained by conventional spectroscopy with a long optical path. Extinction coefficients as low as 1 × 10 -6 liter mole -1 cm -1 have been accurately determined. The sensitivity of the technique has been further demonstrated by measuring the S 0 → T 1 absorption of anthracene; the spectrum compares favorably with results obtained by conventional techniques.