Recyclable and Magnetically Functionalized Metal–Organic Framework Catalyst: IL/Fe3O4@HKUST-1 for the Cycloaddition Reaction of CO2 with Epoxides

A recyclable and magnetic nanocomposite catalyst (IL/Fe₃O₄@HKUST-1) was synthesized via grafting ionic liquid (IL) [AEMIm]BF₄ into magnetically functionalized metal-organic framework Fe₃O₄@HKUST-1 in a water-ethanol media. The properties of IL/Fe₃O₄@HKUST-1 were fully characterized by powder X-ray diffraction, electron microscopy, Fourier-transform infrared spectroscopy, nitrogen adsorption-desorption, density-functional theory, and a magnetic property measurement system. IL/Fe₃O₄@HKUST-1 showed high activity in the solvent-free cycloaddition of CO₂ with epoxides under mild conditions. Furthermore, the catalyst can be easily separated from the reaction mixture, and the recycled catalyst maintained high performance for several cycles. The synergistic effect of the Lewis acid and base sites in IL/Fe₃O₄@HKUST-1 contributes to its greater reactivity than individual IL or HKUST-1.