化学
分解水
氨生产
氮气
电解质
大气压等离子体
氨
大气压力
氢
等离子体
无机化学
电化学
等离子清洗
阳极
分析化学(期刊)
电极
催化作用
光催化
环境化学
物理化学
有机化学
地质学
物理
生物化学
海洋学
量子力学
作者
Pradeep Lamichhane,Bishwa Chandra Adhikari,Linh Nhat Nguyen,Ramhari Paneru,Bhagirath Ghimire,Sohail Mumtaz,Jun Sup Lim,Young June Hong
标识
DOI:10.1088/1361-6595/ab7f4d
摘要
In this study, nitrogen fixation in the electrolyte was achieved by atmospheric pressure non-thermal plasma generated by a sinusoidal power supply (with an applied voltage of 10 kV and frequency of 33 kHz). Ammonia measurements on plasma exposed electrolyte at several working gas and purging gas conditions revealed that nitrogen plasma in the same gas environment is more favourable for plasma-assisted ammonia synthesis. In addition, photo-electrochemical water splitting was performed by irradiating UV light on a titanium dioxide semiconductor photo-anode to generate hydrogen donor in nitrogen reduction reaction. The amount of ammonia synthesized by this synergistic process of photo-electrochemical water splitting and nitrogen plasma is six times higher than that obtained by nitrogen plasma alone. An increase in the co-synthesized NOX concentrations and background contamination at reaction site reduces the ammonia synthesis rate and Faraday efficiency. However, the ammonia production efficiency was increased up to 72% by using a proton-exchange membrane which prevents the diffusion of oxygen evolved from water splitting into the plasma, and by reducing the axial distance between the plasma electrode and reaction site. The sustainable nitrogen fixation process reported herein can be performed at atmospheric pressure conditions without a direct input of hydrogen gas or any catalyst.
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