材料科学
电介质
陶瓷
微观结构
烧结
原子堆积因子
极化率
相对介电常数
离子键合
温度系数
介电常数
矿物学
复合材料
化学工程
分析化学(期刊)
离子
核磁共振
有机化学
光电子学
分子
物理
工程类
化学
作者
Congling Yin,Zezong Yu,Longlong Shu,Laijun Liu,Liyan Yang,Chunchun Li
标识
DOI:10.1016/j.ceramint.2020.09.134
摘要
In this work, compositional modification was proposed to improve the sintering behavior of Li4WO5 via MgO additive. A series of (1-x)Li4WO5-xMgO ceramics were prepared by a simple solid-state reaction route. Solid solutions between Li4WO5 and MgO were formed due to their same crystal structure and the similar ionic sizes. MgO modification improved the microstructure and densification, which in turn increased the dielectric performances of Li4WO5. A composition with x = 0.075 possessed a combination of optimum dielectric properties with a relative permittivity (εr) of 10.8, a quality factor (Q×f) of 26,270 GHz, and a temperature coefficient of resonance frequency (τf) of −8 ppm/°C. The evolutions in dielectric properties with composition were studied from internal effects (ionic polarizability, and packing fraction) and external contributions (density variation). Competing effects from extrinsic and intrinsic contributions give rise to improvements in dielectric properties.
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