Stabilization of heavy metal-contaminated soils by biochar: Challenges and recommendations

Various types of biochar have been widely used to remediate soil contamination from heavy metals (HMs) and to reduce HM mobility and bioavailability in soils in recent years. Most researchers have paid attention to the beneficial effects of biochar during the remediation process, but few have emphasized their negative effects and the challenges for their application. In this review, the negative effects and challenges of applying biochar for the remediation of HM-contaminated soils are thoroughly summarized and discussed, including the changeable characteristics of biochar, biochar over-application, toxic substances in biochar, activation of some HMs in soils by biochar, nonspecific adsorption, and the negative influences of biochar on soil microorganisms and plants. In addition, further research directions and several recommendations (standardization, long-term field experiments, mechanisms research and designer biochars) were also proposed to enable the large-scale application of biochar for the remediation of HM-contaminated soils.