电负性
硫系化合物
电荷(物理)
散射
兴奋剂
带隙
离子
声子
接受者
材料科学
凝聚态物理
化学
原子物理学
光电子学
物理
有机化学
光学
量子力学
作者
Jin Sik Choe,Chang‐Hoon Lee,Min Ji Kim,Gil-Geun Lee,Jong Hyun Shim,Young Soo Lim
摘要
We present site-dependent Sb-doping effects and optical phonon scattering-limited charge transport properties in a layered chalcogenide SnSe2. It was found that a group V element Sb acts as an electron acceptor at the cation site of Sn and as an electron donor at the anion site of Se in SnSe2 compounds. This phenomenon could be interpreted successfully by analyzing Bader atomic net charge, which is strongly affected by the difference of electronegativity between the elements. The charge transport mechanism in SnSe2, which had been controversial, was found to be optical phonon scattering with T−5/2-dependence, and the bandgap was measured to be ∼1.0 eV.
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