纳米棒
咪唑酯
催化作用
材料科学
选择性
水溶液
多孔性
化学工程
蚀刻(微加工)
沸石咪唑盐骨架
金属有机骨架
纳米技术
无机化学
化学
复合材料
物理化学
有机化学
吸附
图层(电子)
工程类
作者
Yuqun Su,Heng Xu,Jiajia Wang,Xikuo Luo,Zheng Xu,Kefu Wang,Wenzhong Wang
出处
期刊:Nano Research
[Springer Nature]
日期:2018-12-28
卷期号:12 (3): 625-630
被引量:47
标识
DOI:10.1007/s12274-018-2269-4
摘要
Imidazolate-based ZIF-8 catalysts M@ZIF-8 (M = Au NR, Au@Ag NR, or Au@PtAg NRT; NR = nanorod, NRT = nanorattle), were assembled. Au NRs acted as the core for the epitaxial growth of the Ag shell, and oxidative etching of Au@Ag NRs led to Au@PtAg NRTs with K2PtCl4 aqueous solution. All metal nanorods (MNRs) and metal nanorattles (MNRTs) were well dispersed and fully encapsulated in ZIF-8. Au@PtAg NRTs encapsulated in ZIF-8 could lead to enhanced stability and selectivity for catalytic applications, combining the advantages of ZIF-8 (tailorable porosity) with the high surface area and improved optical sensitivity of rod-shaped NRTs. The catalyst Au@PtAg@ZIF-8 exhibited efficient catalytic activity and CO selectivity for the gas-phase photoreduction of CO2 with H2O.
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