Preparation of FeNi-based nanoporous amorphous alloy films and their electrocatalytic oxygen evolution properties

The progress of this research is the preparation of FeNi alloy thin films by magnetron sputtering. Each step of the experimental process is based on the electrocatalytic performance of the sample, and characterized by many characterizations means such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), X-ray energy spectrometry (EDS) and step gauge thickness test for morphology, structure and elemental composition, etc. The analysis of the characterization results is used as a support for the experimental process. Adjustment of various preparation process parameters for material growth and subsequent processing include doping of non-metallic elements and construction of nanostructures. Doping of C elements can make FeNi based alloy films further amorphous. Zn element is used as a pore-forming agent. The two processes of doping and high-temperature vacuum dealloying can make the film obtain a nanoporous structure, which greatly increases the specific surface area. These two strategies reduce the overpotential (η10) of oxygen evolution reaction (OER) of FeNi alloy thin films to 393 mV and 314 mV, which are reduced by 47 mV and 79 mV step by step. The electrochemical properties of the finally obtained alloy film are: overpotential of 314 mV, Tafel slope of 61.8 mV/dec and the stability of only 10% decay at a current density of 10 mA/cm2 for 12 h. In this study, low-cost transition metals were used as the main materials to design OER catalysts, and the catalytic efficiency was comparable to that of commercial noble metal catalysts. The physical preparation methods made each sample have good reproducibility. It provides the experimental basis and theoretical basis for the design and synthesis of new catalytic materials at a higher level.