弗里德尔-克拉夫茨反应
酰化
化学
电
有机化学
催化作用
电气工程
工程类
作者
Chen Liu,Jiage Yu,Liang Bao,Gaoyuan Zhang,Xinyue Zou,Bing Zheng,Yiyi Li,Yunfei Zhang
标识
DOI:10.1021/acs.joc.2c03071
摘要
An electricity-promoted method for Friedel-Crafts acylation of biarylcarboxylic acids is described in this research. Various fluorenones can be accessed in up to 99% yields. During the acylation, electricity plays an essential role, which might motivate the chemical equilibrium by consuming the generated TFA. This study is predicted to provide an avenue to realize Friedel-Crafts acylation in a more environmentally friendly process.
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