弗里德尔-克拉夫茨反应
酰化
化学
电
有机化学
催化作用
电气工程
工程类
作者
Chen Liu,Jiage Yu,Liang Bao,Gaoyuan Zhang,Xinyue Zou,Bing Zheng,Yiyi Li,Yunfei Zhang
标识
DOI：10.1021/acs.joc.2c03071
摘要
An electricity-promoted method for Friedel–Crafts acylation of biarylcarboxylic acids is described in this research. Various fluorenones can be accessed in up to 99% yields. During the acylation, electricity plays an essential role, which might motivate the chemical equilibrium by consuming the generated TFA. This study is predicted to provide an avenue to realize Friedel–Crafts acylation in a more environmentally friendly process.
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