倍半硅氧烷
材料科学
膜
多孔性
电池(电)
锂(药物)
化学工程
复合材料
聚合物
医学
功率(物理)
遗传学
物理
量子力学
工程类
生物
内分泌学
作者
Jing-ju Liu,Yuhua Huang,Xiaojie Zhang,Yuxin Ding,Huan Liu,Xuefeng Gui
标识
DOI:10.1016/j.matlet.2024.136162
摘要
As an emerging alternative separator, electrospun PVDF-HFP (polyvinylidene fluoride-hexafluoropropylene) has been widely studied in lithium battery over the years. However, some shortcomings of PVDF-HFP have limited its further application, such as, poor thermal stability, mechanical and electrochemistry properties. In this work, the cage-like silsesquioxanes (CSQ) and metal–organic-framework (MOF) were chemically bound to PVDF-HFP, and a modified hybrid fibrous membrane with hierarchical pore was fabricated. These hybrid groups were successfully introduced into the backbone of PVDF-HFP, which was not only demonstrated by characterization of their chemical structures, and also demonstrated by morphologies and elemental mass spectrometry with the help of scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS). Due to the incorporation of these hybrid groups, the membrane exhibited high thermal stabilities and good flame-retardant performance, and could also play an important role in regulating and improving the migration property of lithium ions and interface performance between electrolyte and electrodes during battery charging/discharging process.
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