Thiol and thioether-based metal–organic frameworks: synthesis, structure, and multifaceted applications

.). The second approach to synthesize thiol and thioether-based MOFs is indirect methods, where thiol or thioether functionality is introduced in MOFs by techniques like post-synthetic modifications (PSM), post-synthetic exchange (PSE) and by forming composite materials. Generally, MOFs containing only thiol-thioether-based ligands are synthesized by interfacial assisted synthesis, forming two-dimensional sheet frameworks, and show significantly high conductivity. A limited study has been done on MOFs containing thiol-thioether-based azolate ligands where both nitrogen- and sulfur-containing functionality are present in the MOF frameworks. These materials exhibit intriguing properties stemming from the interplay between metal centres, organic ligands, and sulfur functionality. As a result, they offer great potential for multifaceted applications, ranging from catalysis, sensing, and conductivity, to adsorption. This perspective is organised through an introduction, schematic representations, and tabular data of the reported thiol and thioether MOFs and concluded with future directions.