催化作用
氨
亚硝酸盐
电解质
纳米颗粒
生物量(生态学)
无机化学
选择性催化还原
电化学
碳纤维
材料科学
法拉第效率
化学工程
化学
核化学
纳米技术
电极
有机化学
硝酸盐
复合数
工程类
物理化学
地质学
复合材料
海洋学
作者
Xiuhong Li,Zerong Li,Longcheng Zhang,Donglin Zhao,Jun Li,Shengjun Sun,Lisi Xie,Qian Liu,Abdulmohsen Ali Alshehri,Yonglan Luo,Yunwen Liao,Qingquan Kong,Xuping Sun
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2022-01-01
卷期号:14 (36): 13073-13077
被引量:11
摘要
Electrocatalytic nitrite (NO2-) reduction to ammonia (NH3) can not only synthesize value-added NH3, but also remove NO2- pollutants from the environment. However, the low efficiency of NO2--to-NH3 conversion hinders its applications. Here, Ni nanoparticle-decorated juncus-derived biomass carbon prepared at 800 °C (Ni@JBC-800) serves as an efficient catalyst for NH3 synthesis by selective electroreduction of NO2-. This catalyst shows a remarkable NH3 yield of 4117.3 μg h-1 mgcat.-1 and a large faradaic efficiency of 83.4% in an alkaline electrolyte. The catalytic mechanism is further investigated by theoretical calculations.
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