化学
对映体
立体化学
羟甲基
生物碱
阿拉伯糖
立体选择性
有机化学
木糖
催化作用
发酵
作者
D.Wyn C. Jones,Robert J. Nash,E. A. Bell,J. M. Williams
标识
DOI:10.1016/s0040-4039(00)98635-0
摘要
The {=D}-xylo and {=L}-arabino isomers of 1,4-dideoxy-1,4-iminopentitol have been synthesised from {=L}-arabinose, and the {=L}-arabino isomer was found to be the enantiomer of the alkaloid from Angylocalyx Boutiqueanus. The alkaloid from Arachniodes Standishii, recently reported to have the xylo configuration, was also shown to be the {=D}-arabino isomer.
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