催化作用
沸石
催化裂化
选择性
开裂
烯烃纤维
焦炭
庚烷
乙烯
酸强度
无机化学
材料科学
ZSM-5型
化学
有机化学
作者
Xinshan Song,Yong‐Guan Zhu,Yajie Tian,Xinyu He,Longhui Guo,Congzhen Qiao,Guozhu Liu
标识
DOI:10.1016/j.joei.2022.03.008
摘要
Series Fe–Al isomorphous and self–pillared ZSM–5 nanosheets zeolite (Al–Fe–SPZ) with different Fe/Al molar ratios were synthesized by one–pot strategy for catalytic cracking of n–heptane to produce light olefins. All the Al–Fe–SPZ catalysts gave high surface areas and pore volumes, ascribing to the intersection of nanosheet layers. The addition of Fe in zeolite framework resulted in the decrease of surface acid concentrations (especially the strong acid concentrations). The effect of Fe modification on olefins selectivity in catalytic cracking reaction had two sides. On one hand, reducing the amount of acid, helped to inhibit the hydride transfer, cyclization and aromatic cyclization of olefins in the product at adjacent Brønsted acid sites. However, the reduced acid concentrations led to the decrease of the cracking depth, and the cracking of intermediate products (C4 and C5) was inhibited, thus giving a decreased olefin selectivity. With Si/(Al+Fe) molar ratio of 100 and Al/Fe ratio of 84/16, Al–Fe–SPZ catalyst gave the highest yield of light olefins (44.8 wt% of ethylene and propylene) in cracking of n–heptane. In addition, Fe modified zeolite catalyst show excellent cracking stability with low coke deposition.
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