Electrocatalytic Hydrogenation of Olefins

Electrochemical synthesis offers a powerful and sustainable alternative to conventional chemical manufacturing techniques. The direct and selective electrohydrogenation of olefins has enormous potential applicability; however, this reactivity has not been sufficiently demonstrated. Herein, we show that an efficient Pt-based electrocatalyst from commercially available PtCl₂ can promote such transformations. This approach enables olefins to be electrohydrogenated (often below -3.0 V vs. Ag/AgCl) at high current density (J_Geo up to 133 mA cm^-2) using protons and electrons as the hydrogen source. This reaction exhibits broad functional group compatibility, requires low catalyst loading, and affords a diverse series of valuable molecules (more than 60 examples) with high chemoselectivity. In addition, highly regioselective electrocatalytic hydrogenation of olefins (r.r. > 19:1) is demonstrated using PtCl₂ and 2,2'-bipyridine.