Quantum Spin Exchange Interactions Trigger O p Band Broadening for Enhanced Aqueous Zinc‐Ion Battery Performance

Abstract The pressing demand for large‐scale energy storage solutions has propelled the development of advanced battery technologies, among which zinc‐ion batteries (ZIBs) are prominent due to their resource abundance, high capacity, and safety in aqueous environments. However, the use of manganese oxide cathodes in ZIBs is challenged by their poor electrical conductivity and structural stability, stemming from the intrinsic properties of MnO 2 and the destabilizing effects of ion intercalation. To overcome these limitations, our research delves into atomic‐level engineering, emphasizing quantum spin exchange interactions (QSEI). These essential for modifying electronic characteristics, can significantly influence material efficiency and functionality. We demonstrate through density functional theory (DFT) calculations that enhanced QSEI in manganese oxides broadens the O p band, narrows the band gap, and optimizes both proton adsorption and electron transport. Empirical evidence is provided through the synthesis of Ru−MnO 2 nanosheets, which display a marked increase in energy storage capacity, achieving 314.4 mAh g −1 at 0.2 A g −1 and maintaining high capacity after 2000 cycles. Our findings underscore the potential of QSEI to enhance the performance of TMO cathodes in ZIBs, pointing to new avenues for advancing battery technology