质子
电导率
膜
金属有机骨架
金属
质子输运
化学
氨基酸
质子交换膜燃料电池
质子导体
材料科学
无机化学
高分子化学
化学工程
物理化学
有机化学
物理
核物理学
生物化学
吸附
工程类
作者
Shubo Wang,H Luo,Xuan Li,Lei Shi,Bowen Cheng,Zhenhuan Li
标识
DOI:10.1016/j.ijhydene.2020.09.235
摘要
Proton conduction is a ubiquitous fundamental phenomenon in biological systems. Biology has solved the problem of energy-related proton conduction, in which the exposed amino acids in the protein ordered channels play a key role in proton conduction. In this contribution, amino acids (glutamate, lysine, and threonine) were attached to metal organic framework (MOF) nanoparticles, which were incorporated into sulfonated polysulfone matrix forming bio-proton channels for the nanocomposite membranes. It is shown in the results that the amino acid-functionalized MOF can help to enhance the proton conductivity and the proton exchange membrane with glutamate-functionalized MOF demonstrate excellent proton conductivity of 0.212 S cm−1 at 80 °C and 100% relative humidity. Meanwhile, the methanol permeability coefficient of the nanocomposite membrane is reduced to 5.8 × 10−7 cm2 s−1. The nanocomposite membranes demonstrate excellent proton conductivity, dimensional stabilities, water absorption, and resistance to methanol performance. Therefore, this material is promising for fuel cells.
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